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81 |
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Answers:
| molecule |
|
idealized line spectrum |
| RCH2-CH3 |
|
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| RCH2-CH2R' |
|
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| RCH2-CHR2' |
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| RCH2-CR3' |
|
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Any mistakes? Then check here for some hints
and explanations!
A measurement for the intensity of the coupling between
two groups A and X of equivalent protons is the coupling constant
JAX:
|
JAX |
= |
Seperation of two neighboring lines in a multiplet, determined
in Hertz |
|
As an example, the following detail of a 1H NMR spectrum
shows the doublet of the methyl protons in the molecule
(CH3)3CH-O-CH(CH3)2 around
d = 1.05 ppm (Transmitter frequency
n0 = 60 MHz):
What is the value for the coupling constant
JCH3,CH?
Continue on page 82 for the answer and an additional
problem!
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